Sæson | Topscorer | Klub | Mål |
|---|
| 2009/10 | Messi, Lionel | FC Barcelona | 34 |
| 2008/09 | Diego Forlán | Club Atlético de Madrid | 32 |
| 2007/08 | Daniel Güiza | RCD Mallorca | 27 |
| 2006/07 | Ruud van Nistelrooy | Real Madrid CF | 25 |
| 2005/06 | Samuel Eto'o | FC Barcelona | 26 |
| 2004/05 | Diego Forlán | Villarreal CF | 25 |
| 2003/04 | Ronaldo Luiz Nazário de Lima | Real Madrid CF | 24 |
| 2002/03 | Roy Makaay | RC Deportivo La Coruña | 29 |
| 2001/02 | Diego Tristan | RC Deportivo La Coruña | 21 |
| 2000/01 | Raúl González | Real Madrid CF | 25 |
| 1999/00 | Salva Ballesta | Real Racing Club Santander | 27 |
| 1998/99 | Raúl González | Real Madrid CF | 25 |
| 1997/98 | Christian Vieri | Club Atlético de Madrid | 24 |
| 1996/97 | Ronaldo Luiz Nazário de Lima | FC Barcelona | 34 |
| 1995/96 | Juan António Pizzi | CD Tenerife | 31 |
| 1994/95 | Ivan Zamorano | Real Madrid CF | 28 |
| 1993/94 | Romário de Souza Faria | FC Barcelona | 30 |
| 1992/93 | Bebeto | RC Deportivo La Coruña | 30 |
| 1991/92 | Manuel Sánchez Manolo | Club Atlético de Madrid | 27 |
| 1990/91 | Emilio Butragueño | Real Madrid CF | 19 |
| 1989/90 | Hugo Sánchez | Real Madrid CF | 38 |
| 1988/89 | Maria de Morais Baltazar | Club Atlético de Madrid | 35 |
| 1987/88 | Hugo Sánchez | Real Madrid CF | 29 |
| 1986/87 | Hugo Sánchez | Real Madrid CF | 34 |
| 1985/86 | Hugo Sánchez | Real Madrid CF | 22 |
| 1984/85 | Hugo Sánchez | Club Atlético de Madrid | 19 |
| 1983/84 | Juan Gómez "Juanito" | Real Madrid CF | 17 |
| 1983/84 | Da Silva | Real Valladolid CF | 17 |
| 1982/83 | Hipólito Rincon | Real Betis Balompié | 20 |
| 1981/82 | Enrique Castro González "Quini" | FC Barcelona | 26 |
| 1980/81 | Enrique Castro González "Quini" | FC Barcelona | 20 |
| 1979/80 | Enrique Castro González "Quini" | Real Sporting de Gijón | 24 |
| 1978/79 | Hans Krankl | FC Barcelona | 29 |
| 1977/78 | Mario Kempes | Valencia CF | 28 |
| 1976/77 | Mario Kempes | Valencia CF | 24 |
| 1975/76 | Enrique Castro González "Quini" | Real Sporting de Gijón | 21 |
| 1974/75 | Carlos | Club Atlético de Bilbao | 19 |
| 1973/74 | Enrique Castro González "Quini" | Real Gijón | 20 |
| 1972/73 | Marianin | Real Oviedo CF | 20 |
| 1971/72 | Porta | Granada CF | 20 |
| 1970/71 | José Eulogio Gárate Ormachea | Club Atlético de Madrid | 17 |
| 1970/71 | Carlos Rexach Cerda | CF Barcelona | 17 |
| 1969/70 | José Luís Aragones | Club Atlético de Madrid | 16 |
| 1969/70 | Amancio Amaro Varela | Real Madrid CF | 16 |
| 1969/70 | José Eulogio Gárate Ormachea | Club Atlético de Madrid | 16 |
| 1968/69 | José Eulogio Gárate Ormachea | Club Atlético de Madrid | 14 |
| 1968/69 | Amancio Amaro Varela | Real Madrid CF | 14 |
| 1967/68 | Uriarte | Club Atlético de Bilbao | 22 |
| 1966/67 | "Waldo" Machado da Silva | Valencia CF | 24 |
| 1965/66 | Edvaldo Izidio Neto "Vavá" | Elche CF | 19 |
| 1964/65 | Cayetano Ré Ramírez | CF Barcelona | 25 |
| 1963/64 | Ferenc Puskás | Real Madrid CF | 20 |
| 1962/63 | Ferenc Puskás | Real Madrid CF | 26 |
| 1961/62 | Juan Seminario | Real Zaragoza | 25 |
| 1960/61 | Ferenc Puskás | Real Madrid CF | 27 |
| 1959/60 | Ferenc Puskás | Real Madrid CF | 28 |
| 1958/59 | Alfredo Di Stefano | Real Madrid CF | 23 |
| 1957/58 | Ricardo | Valencia CF | 19 |
| 1957/58 | Badenes | Real Valladolid CF | 19 |
| 1957/58 | Alfredo Di Stefano | Real Madrid CF | 19 |
| 1956/57 | Alfredo Di Stefano | Real Madrid CF | 31 |
| 1955/56 | Alfredo Di Stefano | Real Madrid CF | 24 |
| 1954/55 | Juan Arza Iñigo | Sevilla CF | 28 |
| 1953/54 | Alfredo Di Stefano | Real Madrid CF | 29 |
| 1952/53 | Telmo Zarraondia Montoya "Zarra" | Club Atlético de Bilbao | 24 |
| 1951/52 | Pahiño | Real Madrid CF | 28 |
| 1950/51 | Telmo Zarraondia Montoya "Zarra" | Club Atlético de Bilbao | 38 |
| 1949/50 | Telmo Zarraondia Montoya "Zarra" | Club Atlético de Bilbao | 25 |
| 1948/49 | César Rodríguez Alvarez | CF Barcelona | 28 |
| 1947/48 | Pahiño | RC Celta de Vigo | 23 |
| 1946/47 | Telmo Zarraondia Montoya "Zarra" | Club Atlético de Bilbao | 34 |
| 1945/46 | Telmo Zarraondia Montoya "Zarra" | Club Atlético de Bilbao | 24 |
| 1944/45 | Telmo Zarraondia Montoya "Zarra" | Club Atlético de Bilbao | 19 |
| 1943/44 | Edmundo Suárez "Mundo" | Valencia CF | 27 |
| 1942/43 | M. Martín | CF Barcelona | 32 |
| 1941/42 | Edmundo Suárez "Mundo" | Valencia CF | 27 |
| 1940/41 | Pruden | Atlético Aviación de Madrid | 30 |
| 1939/40 | Unamuno | Club Atlético de Bilbao | 20 |
| 1935/36 | Isidoro Lángara Galárraga | Real Oviedo CF | 27 |
| 1934/35 | Isidoro Lángara Galárraga | Real Oviedo CF | 26 |
| 1933/34 | Isidoro Lángara Galárraga | Oviedo CF | 27 |
| 1932/33 | Manolo Olivares | Real Madrid CF | 16 |
| 1931/32 | Guillermo Gorostiza Paredes | Athletic Club de Bilbao | 12 |
| 1930/31 | Bata | Athletic Club de Bilbao | 29 |
| 1929/30 | Guillermo Gorostiza Paredes | Athletic Club de Bilbao | 20 |
| 1928/29 | Francisco "Cuqui" Bienzobas | Real Sociedad de Fútbol | 14 |
